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Master mode
Successfully complete Musou mode on the Easy or Normal difficulty to unlock the Master difficulty for Musou mode and Free mode.
Chaos mode
Successfully complete Musou mode with a character from the Wu, Shu, Wei, and Other factions to unlock the Chaos difficulty.
Alternate costume
Reach level 25 with a character in any mode to unlock his or her second costume.
Voice Gallery
Reach level 50 with a character in any mode to unlock his or her Voice Gallery.
Movie Player
Successfully complete Musou mode to unlock the Movie Player.
Bonus characters
Successfully complete the indicated task to unlock the corresponding character:
Cao Cao: Successfully complete Musou mode with three Wei characters.
Cao Pi: Defeat Cao Pi in less than five minutes on the Sun Jian side of He Fei.
Cao Ren: Successfully complete Battle Objective 2 on the Lu Bu side of Fan Castle.
Diao Chan: Successfully complete Musou mode with one character from each kingdom.
Dong Zhuo: Successfully complete Battle Objective 1 on the Lu Bu side of The Battle Of Hu Lao Gate.
Gan Ning: Successfully complete Musou mode with a Wu character.
Guan Ping: Successfully complete Battle Objective 2 on the Shu side of Fan Castle, and finish the battle with Guan Ping surviving.
Huang Gai: Successfully complete Battle Objective 3 on the Wu side of The Battle of Chi Bi.
Huang Zhong: Successfully complete Battle Objective 1 on the Wei side of Ding Jun Mountain.
Ling Tong: Successfully complete Battle Objective 1 on the Wei side of the Battle of Shi Ting.
Liu Bei: Successfully complete Musou mode with three Shu characters.
Lu Bu: Successfully complete Musou mode with Liu Bei, Cao Cao, Diao Chan, and Sun Jian.
Lu Meng: Successfully complete Battle Objective 2 on the Wei side of He Fei.
Ma Chao: Successfully complete Battle Objective 2 on the Wei side of Han Zhong Attack Defense Battle.
Pang Tong: Successfully complete Battle Objective 3 at the Cheng Du battle, and finish the battle with Pang Tong surviving.
Sun Ce: Successfully complete Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi.
Sun Jian: Successfully complete Musou mode with three Wu characters.
Sun Quan: Successfully complete Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi.
Taishi Ci: Defeat Taishi Ci in the Battle For Wu Territory.
Wei Yan: Successfully complete Battle Objective 2 on the Shu side of Wu Zhang Plains, and finish the battle with Wei Yan surviving.
Xiahou Yuan: Successfully complete Battle Objective 1 on the Shu side of Ding Jun Mountain.
Xiao Quio: Successfully complete Battle Objective 3 on the Wu side of the Battle of Shi Ting.
Xu Zhu: Personally kill Cao Ren and Xu Chu on the Wu side of He Fei.
Xu Huang: Successfully compelte Battle Objective 2 on the Wei or Wu side of Fan Castle.
Yue Ying: Successfully complete Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains.
Zhang Jiao: Defeat Zhang Jiao in the Yellow Turban Rebellion.
Zhang Liao: Successfully complete Musou mode with a Wei character.
Zhen Ji: Successfully complete Battle Obective 1 on the Lu Bu side of Xu Du Invasion Battle.
Zheng He: Successfully complete Battle Objective 2 on the Shu side of Han Zhong Attack Defense Battle.
Zhou Tai: Successfully complete Battle Objective 3 on the Shu side of Yi Ling.
Zhuge Liang: Successfully complete Musou mode with a Shu character.
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